Multiple Choice Identify the
choice that best completes the statement or answers the question.
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1.
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All of the following are homogeneous mixtures except
a. | soil. | c. | gasoline. | b. | a sugar-water solution. | d. | a salt-water
solution. |
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2.
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An endothermic dissolution process
a. | absorbs energy as heat and has positive enthalpy of solution. | b. | releases energy as
heat and has positive enthalpy of solution. | c. | absorbs energy as heat and has negative
enthalpy of solution. | d. | releases energy as heat and has negative
enthalpy of solution. |
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3.
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As temperature increases, solubility of solids in liquids
a. | always increases. | c. | usually increases. | b. | always decreases. | d. | usually
decreases. |
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4.
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What is the molality of a solution that contains 5.10 mol KNO3 in
4.47 kg water? (molar mass of KNO3 = 101.11 g/mol)
a. | 0.315 m | c. | 1.02 m | b. | 0.779 m | d. | 1.14 m |
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5.
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The hydrogen ion
a. | has a charge of 2+. | c. | has a negative
charge. | b. | is a proton. | d. | is a bare electron. |
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6.
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Nonvolatile solutes
a. | depress freezing point and elevate boiling point. | b. | elevate freezing
point and depress boiling point. | c. | depress both freezing point and boiling
point. | d. | elevate both freezing point and boiling point. |
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7.
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Actual freezing-point depressions of electrolyte solutions are slightly lower
than the calculated values because of
a. | ion repulsion. | b. | more complete ionization than is
expected. | c. | ion attraction. | d. | higher-than-expected effective
concentration. |
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8.
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Acetic acid is found in
a. | lemons. | c. | sour milk. | b. | vinegar. | d. | apples. |
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9.
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Which of the following is chlorous acid?
a. | HClO | c. | HClO3 | b. | HClO2 | d. | HClO4 |
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10.
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An electron-pair acceptor is a(n)
a. | Brønsted-Lowry base. | c. | Lewis base. | b. | Lewis
acid. | d. | Arrhenius
acid. |
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11.
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If [H3O+] = 1.7 ´ 10–3 M, what is the pH of the solution?
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12.
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What process measures the amount of a solution of known concentration required
to react with a measured amount of a solution of unknown concentration?
a. | autoprotolysis | c. | neutralization | b. | hydrolysis | d. | titration |
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13.
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An acid-base titration determines the volumes of two solutions that
a. | are chemically equivalent. | c. | have equal
mass. | b. | have equal molarity. | d. | have equal molality. |
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14.
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What is the molarity of an HCl solution if 50.0 mL is neutralized in a titration
by 40.0 mL of 0.400 M NaOH?
a. | 0.200 M | c. | 0.320 M | b. | 0.280 M | d. | 0.500 M |
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15.
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Which of the following best describes temperature?
a. | energy as heat absorbed or released in a chemical or physical
change | b. | a measure of the average kinetic energy of the particles in a sample of
matter | c. | energy in the form of heat | d. | energy of
change |
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16.
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What units are used to measure energy as heat?
a. | joules/mole or kilojoules/mole | c. | joules or
kilojoules | b. | kelvins or degrees Celsius | d. | None of the above |
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17.
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A reaction is spontaneous if 
is
a. | zero. | c. | positive. | b. | negative. | d. | greater than DH. |
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18.
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What is the value of at 200 K for a
reaction in which  = –150 kJ/mol and = +2.00 kJ/(mol·K)?
a. | –250 kJ/mol | c. | +250 kJ/mol | b. | –450 kJ/mol | d. | +450 kJ/mol |
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19.
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Which branch of chemistry studies reaction mechanisms?
a. | thermochemistry | c. | chemical kinetics | b. | thermodynamics | d. | calorimetry |
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20.
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For most reactions, particles must
a. | collide. | c. | be at rest. | b. | be properly oriented. | d. | collide in the proper
orientation. |
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21.
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Reaction rate depends upon
a. | both collision frequency and efficiency. | b. | average kinetic
energy. | c. | collision efficiency. | d. | average potential
energy. |
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22.
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A sample of a substance burns more rapidly in pure oxygen than in air. Which
factor is most responsible for this high rate of reaction?
a. | the pressure of the reactants | c. | concentration of the
reactants | b. | temperature | d. | surface area exposed to air |
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23.
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The letter k in a rate law stands for
a. | a proportionality constant. | c. | temperature. | b. | concentration. | d. | reaction rate. |
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24.
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In the rate law for the following equation,
R=k[A]n[B]m, the units for [A] and
[B] are
a. | g-1s-1. | c. | M. | b. | M-1s-1. | d. | Ms-1. |
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25.
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What symbol in a chemical equation indicates equilibrium?
a. |  | c. |  | b. |  | d. | None of
the above |
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26.
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In the equation  , what represents the concentrations of the
reactants?
a. | [Y] and [Z] | c. |  | b. | [W] and [X] | d. |  |
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27.
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In the equation,  what represents the concentrations of the
products?
a. | [Y] and [Z] | c. |  | b. | [W] and [X] | d. |  |
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28.
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If a soluble product forms, a reaction may run to completion
a. | if the product is only slightly ionized. | b. | if the product is
highly soluble. | c. | if the product is not gaseous. | d. | under no
circumstances. |
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29.
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Adding sodium acetate to an acetic acid, CH3COOH, solution
a. | increases pH and lowers [H+]. | b. | increases pH and
raises [H+]. | c. | decreases pH and lowers
[H+]. | d. | decreases pH and raises
[H+]. |
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30.
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The cation of the salt of a strong acid and a weak base is the
a. | hydronium ion. | c. | conjugate acid of the weak base. | b. | hydroxide
ion. | d. | conjugate base of the
strong acid. |
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31.
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What is the solubility-product constant of barium carbonate, BaCO3?
Its solubility is 0.0022 g/100 g H2O. The molar mass of BaCO3 is 197.34
g/mol.
a. | 1.2 10–6 | c. | 2.2
10–8 | b. | 1.2 10–8 | d. | 4.4
10–10 |
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32.
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Calculate the ion product for mixing 50 mL of 0.015 M
Ca(NO3)2 with 200 mL of 0.35 M NaOH. Ksp for
Ca(OH)2 is 5.5 ´ 10–6. Does a precipitate
form?
a. | 8.5 ´ 10–7; no | c. | 2.4 ´ 10–4; no | b. | 8.5 ´
10–7; yes | d. | 2.4 ´ 10–4;
yes |
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33.
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In the reaction represented by the equation F 2 + Mg  2F – +
Mg 2+, which species is oxidized?
a. | F2 | c. | Both (a) and (b) | b. | Mg | d. | Neither (a) or
(b) |
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34.
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After balancing the redox equation FeCl2 + KMnO4 + HCl
® FeCl3 + MnCl2 + H2O + KCl, the
coefficients, in order from left to right, are
a. | 3, 1, 4, 3, 1, 2, 1. | b. | 4, 2, 5, 4, 2, 3, 2. | c. | 5, 1, 8, 5, 1, 4,
1. | d. | 5, 1, 4, 5, 1, 4, 1. |
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35.
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Which process deposits metal onto a surface?
a. | electrolysis | c. | autooxidation | b. | electroplating | d. | oxidation |
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36.
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In a cell used to electroplate silver onto an object, Ag+ is
a. | oxidized at the anode. | c. | oxidized at the cathode. | b. | reduced at the
anode. | d. | reduced at the
cathode. |
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37.
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Reactions that affect the nucleus of an atom are called
a. | fusions. | c. | radioactive decays. | b. | fissions. | d. | nuclear
reactions. |
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38.
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Balance the following equation:  + ____ 
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39.
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Balance the following equation:  + ____  + 
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40.
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Which of the following particles has the same mass as an electron but a positive
charge and is sometimes emitted from the nucleus during radioactive decay?
a. | beta particle | c. | positron | b. | alpha particle | d. | gamma ray |
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41.
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A roentgen equals the amount of radiation that produces
a. | 2 1018 ion pairs in 1 cm3
of dry air. | b. | 2 1019 ion pairs in 1 cm3
of dry air. | c. | 2 108 ion pairs in 1 cm3
of dry air. | d. | 2 109 ion pairs in 1 cm3
of dry air. |
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42.
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Radioactive nuclides cause molecules in air to
a. | ionize. | c. | condense. | b. | fluoresce. | d. | radiate. |
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43.
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Each carbon atom in a molecule forms four single covalent bonds with other atoms
in a(n)
a. | aromatic hydrocarbon. | c. | structural isomer. | b. | saturated hydrocarbon. | d. | geometric
isomer. |
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44.
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Which statement about London dispersion forces is correct?
a. | Their strength increases as the mass of the molecule increases. | b. | Their strength
decreases as the mass of the molecule increases. | c. | Their strength increases as the mass of the
molecule decreases. | d. | Their strength does not depend on the mass of
the molecule. |
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45.
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What is the general formula for ethers?
a. | R–O–R' | c. | R–COO–R' | b. | R–COOH | d. | R–CHO |
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46.
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Which of the following compounds is used in cold creams, body lotions, and
lipsticks?
a. | ethanol | c. | glycerol | b. | ethylene glycol | d. | methanol |
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47.
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The monomer of both starch and cellulose is
a. | an amino acid. | c. | sucrose. | b. | glycogen. | d. | glucose. |
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48.
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The two most abundant elements found in lipids are
a. | oxygen and carbon. | c. | carbon and hydrogen. | b. | hydrogen and oxygen. | d. | carbon and
phosphorus. |
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49.
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Energy is needed for
a. | catabolic reactions to occur. | c. | digestion to
occur. | b. | anabolic reactions to occur. | d. | None of the
above |
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50.
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A gene is a sequence of DNA that holds the code for
a. | self-replication. | b. | the manufacture of a
polypeptide. | c. | the manufacture of a carbohydrate. | d. | recombinant
technology. |
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