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Chapter 17 Sample



Multiple Choice
Identify the choice that best completes the statement or answers the question.
 

 1. 

In the reaction represented by the following equation, a possible intermediate is H2(g) + I2(g) mc001-1.jpg 2HI(g)
a.
H2.
c.
H2I.
b.
HI.
d.
I2.
 

 2. 

How many steps are in the pathway when hydrogen iodide forms from its elements?
a.
one
c.
four or five
b.
two or three
d.
five or six
 

 3. 

Which attempts to explain chemical reactions and physical interactions of molecules?
a.
chemical kinetics
c.
thermodynamics
b.
collision theory
d.
thermochemistry
 

 4. 

Activation energy is
a.
the energy required to form the activated complex.
b.
the net energy required to turn reactants into products.
c.
the enthalpy of reaction.
d.
free energy.
 

 5. 

The bonding of the activated complex is characteristic of
a.
reactants only.
c.
both reactants and products.
b.
products only.
d.
solids only.
 

 6. 

An activated complex
a.
always separates into the products.
b.
always re-forms the reactants.
c.
may either separate into the products or re-form the reactants.
d.
always evaporates.
 

 7. 

What takes place in an activated complex?
a.
Bonds form.
b.
Bonds break.
c.
Some bonds form and other bonds break.
d.
A catalyst is produced.
 

 8. 

Which statement correctly describes the energy changes that occur when bonds form and when bonds break?
a.
Breaking bonds is endothermic, and forming bonds is exothermic.
b.
Breaking bonds is exothermic, and forming bonds is endothermic.
c.
Both are exothermic.
d.
Both are endothermic.
 

 9. 

mc009-1.jpg is positive for
a.
an endothermic reaction.
c.
an inhibited reaction.
b.
an exothermic reaction.
d.
a stable reaction.
 

 10. 

Which term has the same numerical value for the forward reaction as it has for the reverse reaction but with opposite sign?
a.
DE
c.
Ea´
b.
mc010-1.jpg
d.
Ea
 

 11. 

The usual condition for reaction, a favorable orientation, is not necessary for
a.
synthesis reactions.
c.
single-displacement reactions.
b.
decomposition reactions.
d.
double-displacement reactions.
 

 12. 

Chemical kinetics studies
a.
the factors that affect the rate of reaction.
b.
the mathematical expressions for the rate of reaction.
c.
the factors that affect the rate of reaction and the mathematical expressions for the rate of reaction.
d.
the effect of quantum kinetics on chemical reactions.
 

 13. 

The study of chemical kinetics requires concentrations that are measured
a.
once.
c.
using a scale.
b.
in meters/second.
d.
frequently.
 

 14. 

How fast something changes with time is a(n)
a.
area.
c.
order.
b.
rate.
d.
collision.
 

 15. 

Reaction rate depends upon
a.
both collision frequency and efficiency.
b.
average kinetic energy.
c.
collision efficiency.
d.
average potential energy.
 

 16. 

Which of the following affects reaction rate?
a.
the nature of reactants
c.
temperature
b.
surface area of reactants
d.
All of the above
 

 17. 

Which of the following burns most slowly?
a.
a large lump of coal
c.
powdered coal
b.
small pieces of coal
d.
All of these burn at the same rate.
 

 18. 

If the surface area of reactants is larger,
a.
the reaction rate is generally higher.
c.
the reaction rate is not affected.
b.
the reaction rate is generally lower.
d.
the rate-determining step is eliminated.
 

 19. 

Doubling the pressure of a gas
a.
increases the concentration by a factor of two.
b.
reduces the concentration by a factor of two.
c.
doesn't affect the concentration.
d.
reduces the concentration by a factor of four.
 

 20. 

Which term describes a catalyst in the same phase as the reactants and products?
a.
homogenous
c.
activated
b.
heterogeneous
d.
inhibited
 

 21. 

According to the rate law, the rate of a reaction and the concentration of reactants are always
a.
equal.
c.
negative.
b.
proportional.
d.
unable to be determined.
 

 22. 

Rate laws are determined by
a.
studying reaction mechanisms.
b.
calculating kinetic energy, frequency of collision, and temperature for a reaction.
c.
applying collision theory to a reaction.
d.
experiment.
 

 23. 

If doubling the concentration of a reactant doubles the rate of the reaction, the concentration of the reactant appears in the rate law with a(n)
a.
exponent of 1.
c.
exponent of 4.
b.
exponent of 2.
d.
coefficient of 2.
 

 24. 

If doubling the concentration of a reactant quadruples the rate of the reaction, the concentration of the reactant appears in the rate law with a(n)
a.
exponent of 1.
c.
exponent of 4.
b.
exponent of 2.
d.
coefficient of 2.
 

 25. 

If a chemical reaction proceeds in a sequence of steps, the slowest step is called
a.
the kinetic step.
c.
the problem step.
b.
the constant step.
d.
the rate-determining step.
 



 
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