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Chapter 5 Sample



Multiple Choice
Identify the choice that best completes the statement or answers the question.
 

 1. 

A mutual electrical attraction between the nuclei and valence electrons of different atoms that binds the atoms together is called a(n)
a.
dipole.
c.
chemical bond.
b.
Lewis structure.
d.
London force.
 

 2. 

As independent particles, most atoms are
a.
at relatively high potential energy.
c.
very stable.
b.
at relatively low potential energy.
d.
part of a chemical bond.
 

 3. 

As atoms bond with each other, they
a.
increase their potential energy, thus creating less-stable arrangements of matter.
b.
decrease their potential energy, thus creating less-stable arrangements of matter.
c.
increase their potential energy, thus creating more-stable arrangements of matter.
d.
decrease their potential energy, thus creating more-stable arrangements of matter.
 

 4. 

If the atoms that share electrons have an unequal attraction for the electrons, the bond is called
a.
nonpolar.
c.
ionic.
b.
polar.
d.
dipolar.
 

 5. 

Nonpolar covalent bonds are not common because
a.
one atom usually attracts electrons more strongly than the other.
b.
ions always form when atoms join.
c.
the electrons usually remain equally distant from both atoms.
d.
dipoles are rare in nature.
 

 6. 

The greater the electronegativity difference between two bonded atoms, the greater the percentage of ____ in the bond.
a.
ionic character
c.
metallic character
b.
covalent character
d.
electron sharing
 

 7. 

The pair of elements that forms a bond with the least ionic character is
a.
Na and Cl.
c.
O and Cl.
b.
K and Cl.
d.
Mg and Cl.
 

 8. 

The B—F bond in BF3 (electronegativity for B is 2.0; electronegativity for F is 4.0) is
a.
polar covalent.
c.
nonpolar covalent.
b.
ionic.
d.
metallic.
 

 9. 

In the three molecules, O2, HCl, and F2, what atom would have a partial negative charge?
a.
oxygen
c.
chlorine
b.
hydrogen
d.
fluorine
 

 10. 

The percentage ionic character and the type of bond in Br2 (electronegativity for Br is 2.8) is
a.
0%; nonpolar covalent.
c.
0%; pure ionic.
b.
100%; polar covalent.
d.
100%; pure ionic.
 

 11. 

A neutral group of atoms held together by covalent bonds is a
a.
molecular formula.
c.
polyatomic ion.
b.
chemical formula.
d.
molecule.
 

 12. 

Which of the following shows the types and numbers of atoms joined in a single molecule of a molecular compound?
a.
molecular formula
c.
covalent bond
b.
potential energy diagram
d.
ionic bond
 

 13. 

Which of the following is not an example of a molecular formula?
a.
H2O
c.
NH3
b.
B
d.
O2
 

 14. 

The energy released when a covalent bond forms is the difference between zero and the
a.
maximum potential energy.
c.
minimum potential energy.
b.
kinetic energy of the atom.
d.
bond length expressed in nanometers.
 

 15. 

In a molecule of fluorine, the two shared electrons give each fluorine atom how many electron(s) in the outer energy level?
a.
1
c.
8
b.
2
d.
32
 

 16. 

The electron configuration of nitrogen is 1s2 2s2 2p3. How many more electrons does nitrogen need to satisfy the octet rule?
a.
1
c.
5
b.
3
d.
8
 

 17. 

In drawing a Lewis structure, the central atom is generally the
a.
atom with the greatest mass.
b.
atom with the highest atomic number.
c.
atom with the fewest electrons.
d.
least electronegative atom.
 

 18. 

To draw a Lewis structure, one must know the
a.
number of valence electrons in each atom.
b.
atomic mass of each atom.
c.
bond length of each atom.
d.
ionization energy of each atom.
 

 19. 

Multiple covalent bonds may occur in atoms that contain carbon, nitrogen, or
a.
chlorine.
c.
oxygen.
b.
hydrogen.
d.
helium.
 

 20. 

What is the correct Lewis structure for hydrogen chloride, HCl?

mc020-1.jpgmc020-2.jpg
a.
A
c.
C
b.
B
d.
D
 

 21. 

Bonding in molecules or ions that cannot be correctly represented by a single Lewis structure is
a.
polyatomic.
c.
single bonding.
b.
resonance.
d.
double bonding.
 

 22. 

In the NaCl crystal, each Na+ and Cl ion has how many oppositely charged ions clustered around it?
a.
1
c.
4
b.
2
d.
6
 

 23. 

In an ionic compound, the orderly arrangement of ions in a crystal is the state of
a.
maximum potential energy.
c.
average potential energy.
b.
minimum potential energy.
d.
zero potential energy.
 

 24. 

The ions in most ionic compounds are organized into a
a.
molecule.
c.
polyatomic ion.
b.
Lewis structure.
d.
crystal.
 

 25. 

In a crystal, the electrons of adjacent ions
a.
repel each other.
c.
neutralize each other.
b.
attract each other.
d.
have no effect on each other.
 

 26. 

The energy released when 1 mol of an ionic crystalline compound is formed from gaseous ions is called the
a.
bond energy.
c.
lattice energy.
b.
potential energy.
d.
energy of crystallization.
 

 27. 

Compared with energies of neutral atoms, a crystal lattice has
a.
higher potential energy.
c.
equal potential energy.
b.
lower potential energy.
d.
less stability.
 

 28. 

Compared with ionic compounds, molecular compounds
a.
have higher boiling points.
c.
have lower melting points.
b.
are brittle.
d.
are harder.
 

 29. 

The forces of attraction between molecules in a molecular compound are
a.
stronger than the forces among formula units in ionic bonding.
b.
weaker than the forces among formula units in ionic bonding.
c.
approximately equal to the forces among formula units in ionic bonding.
d.
zero.
 

 30. 

The properties of both ionic and molecular compounds are related to the
a.
lattice energies of the compounds.
b.
strengths of attraction between the particles in the compounds.
c.
number of covalent bonds each contains.
d.
mobile electrons that they contain.
 

 31. 

The Lewis structure for the ammonium ion, NH4, has
a.
nonpolar covalent bond.
c.
polar covalent bond.
b.
ionic bond.
d.
metallic bond.
 

 32. 

How many extra electrons are in the Lewis structure of the phosphate ion, PO43–?
a.
0
c.
3
b.
2
d.
4
 

 33. 

A chemical bond formed by the attraction between positive ions and surrounding mobile electrons is a(n)
a.
nonpolar covalent bond.
c.
polar covalent bond.
b.
ionic bond.
d.
metallic bond.
 

 34. 

In metals, the valence electrons
a.
are attached to particular positive ions.
c.
are immobile.
b.
are shared by all of the atoms.
d.
form covalent bonds.
 

 35. 

Metals are malleable because the metallic bonding
a.
holds the layers of ions in rigid positions.
b.
maximizes the repulsive forces within the metal.
c.
allows one plane of ions to slide past another.
d.
is easily broken.
 

 36. 

Malleability and ductility are characteristic of substances with
a.
covalent bonds.
c.
Lewis structures.
b.
ionic bonds.
d.
metallic bonds.
 

 37. 

Shifting the layers of an ionic crystal causes the crystal to
a.
be drawn into a wire.
c.
become metallic.
b.
shatter.
d.
emit light.
 

 38. 

According to VSEPR theory, an AB2 molecule is
a.
trigonal-planar.
c.
linear.
b.
tetrahedral.
d.
octahedral.
 

 39. 

According to VSEPR theory, the shape of an AB3 molecule is
a.
trigonal-planar.
c.
linear.
b.
tetrahedral.
d.
bent.
 

 40. 

Use VSEPR theory to predict the shape of the hydrogen chloride molecule, HCl.
a.
tetrahedral
c.
bent
b.
linear
d.
trigonal-planar
 

 41. 

Use VSEPR theory to predict the shape of the chlorate ion, ClO3.
a.
trigonal-planar
c.
trigonal-pyramidal
b.
octahedral
d.
bent
 

 42. 

The mixing of two or more atomic orbitals of similar energies on the same atom to produce new orbitals of equal energies is called
a.
VSEPR theory.
c.
hybridization.
b.
malleability.
d.
dipole-dipole interaction.
 

 43. 

Which hybrid orbitals help explain the bonding in methane, CH4?
a.
sp3 orbitals
c.
pd3 orbitals
b.
sp orbitals
d.
df3 orbitals
 

 44. 

Four hybrid sp3 orbitals are formed from
a.
two s orbitals and two p orbitals.
b.
an s orbital and a p orbital.
c.
three s orbitals and one p orbital.
d.
one s orbital and three p orbitals.
 

 45. 

Dipole-dipole forces are considered the most important forces in polar substances because the London dispersion forces present in polar substances
a.
are no longer present.
b.
are usually much weaker than the dipole-dipole forces.
c.
are too unpredictable.
d.
act only in solids.
 

 46. 

The strength of London dispersion forces between molecules depends on
a.
only the number of electrons in the molecule.
b.
only the number of protons in the molecule.
c.
both the number of electrons in the molecule and the mass of the molecule.
d.
both the number of electrons and the number of neutrons in the molecule.
 

 47. 

The strong forces of attraction between the positive and negative regions of molecules are called
a.
dipole-dipole forces.
c.
lattice forces.
b.
London forces.
d.
orbital forces.
 

 48. 

The equal but opposite charges present in the two regions of a polar molecule create a(n)
a.
electron sea.
c.
crystal lattice.
b.
dipole.
d.
ionic bond.
 

 49. 

A polar molecule contains
a.
ions.
b.
a region of positive charge and a region of negative charge.
c.
only London forces.
d.
no bonds.
 

 50. 

Iodine monochloride (ICl) has a higher boiling point than bromine (Br2) partly because iodine monochloride is a(n)
a.
nonpolar molecule.
c.
metal.
b.
polyatomic ion.
d.
polar molecule.
 



 
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